Electrophilic fluorination using a hypervalent iodine reagent derived from fluoride.
نویسندگان
چکیده
The air and moisture stable fluoroiodane 8, readily prepared on a 6 g scale by nucleophilic fluorination of the hydroxyiodane 7 with TREAT-HF, has been used as an electrophilic fluorinating reagent for the first time to monofluorinate 1,3-ketoesters and difluorinate 1,3-diketones in good isolated yields.
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ورودعنوان ژورنال:
- Chemical communications
دوره 49 81 شماره
صفحات -
تاریخ انتشار 2013